Adjective:

कक्षीय,

orbitals's Usage Examples:

Angle strain (Baeyer strain)AlkanesIn alkanes, optimum overlap of atomic orbitals is achieved at 109.

Also displayed are four simple rectangular areas or blocks associated with the filling of different atomic orbitals.

Out of the three, Gaussian-type orbitals are by far the most often used, as they allow efficient implementations of Post-Hartree–Fock methods.

The other CSFs can be characterised by the number of spin orbitals that are swapped with virtual orbitals from the Hartree"ndash;Fock determinant.

Introduction For the simplest single bond, found in the H2 molecule, molecular orbitals can always be written in terms of two functions χiA and χiB (which are atomic orbitals with small corrections) located at the two nuclei A and B:\varphi_i N_i(\chi_{iA} \pm \chi_{iB}),where Ni is a normalization constant.

One could, for instance, allow only single and double excitations from some strongly occupied subset of active orbitals, or restrict the number of electrons to at most 2 in another subset of active orbitals.

After introducing an anti-bonding orbital\phi_2 N_2 (1s_A - 1s_B),the total wave function of H2 can be written as a linear combination of configurations built from bonding and anti-bonding orbitals:\Psi_\text{MC} C_1 \Phi_1 + C_2 \Phi_2,where Φ2 is the electronic configuration (φ2)2.

The molecular orbitals in this case φ1 are taken as sums of 1s atomic orbitals on both atoms, namely N1(1sA"nbsp;+"nbsp;1sB).

sp3-hybridized orbitals, but single bonds formed between carbon atoms with other hybridizations do occur (e.

They allow a delocalization of π electrons across all the adjacent aligned p orbitals.

However, the intrinsic symmetry of these complexes is already tetragonal and no degenerate eg orbital exists, having split into a1g (mainly 3z^2-r^2) and b1g (mainly x^2-y^2) orbitals due to the different electronic interactions with axial X ligands and equatorial Y ligands.

follows: Atomic s character concentrates in orbitals directed toward electropositive substituents.

In octahedral symmetry the d-orbitals.