फेरोसाइनिक एसिड का नमक आमतौर पर लौह सल्फेट के साथ साइनाइड की प्रतिक्रिया द्वारा प्राप्त किया जाता है

ferrocyanide शब्द के हिंदी अर्थ का उदाहरण:

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ferrocyanide's Usage Examples:

Rossler and Hasslacher prepare the double potassium sodium cyanide by fusing potassium ferrocyanide with sodium, the product of fusion being extracted with water and the solution evaporated: K 4 Fe(NC) 6 +2Na = Fe+ 4KNC 2NaNC. This process gives a product free from cyanate, which was always formed in the older fusion processes.

It may also be prepared by heating formic and oxalic acids (or their salts) with concentrated sulphuric acid (in the case of oxalic acid, an equal volume of carbon dioxide is produced); and by heating potassium ferrocyanide with a large excess of concentrated sulphuric acid, K 4 Fe(CN) 6 -i-6H2S04+6H20=2K2S04+FeS04+3(NH4)2S04+6C0.

They are soluble in water and give characteristic precipitates with platinic and auric chlorides, and with potassium ferrocyanide.

Of the principal workers in this field we may notice Friedrich Hoffmann, Andreas Sigismund Marggraf (who detected iron by its reaction with potassium ferrocyanide, and potassium and sodium by their flame colorations), and especially Carl Scheele and Torbern Olof Bergman.

Ammonia gives a characteristic blue coloration when added to a solution of a copper salt; potassium ferrocyanide gives a brown precipitate, and, if the solution be very dilute, a brown colour is produced.

Potassium cyanide may be obtained by fusing potassium ferrocyanide either alone - K4Fe(NC)6=4KNC+ FeC2+N2 - or with potassium carbonate [V.

The most modern and the most generally accepted method is volumetric, and is based on the reaction between zinc chloride and potassium ferrocyanide, by which insoluble zinc ferrocyanide and soluble potassium chloride are formed; the presence of the slightest excess of potassium ferrocyanide is shown by a brownish tint being imparted by the solution to a drop of uranium nitrate.

He mentioned as an important exception the case of ferric ferrocyanide, which, when dissolved in oxalic acid, transmits the rays in great abundance, though the same rays be absorbed both by ferrocyanides and by ferric salts.

Quinone-dioxime, HON: C 6 H 4: NOH, crystallizes in colourless or yellow needles, which decompose when heated to about 240° C. Potassium ferrocyanide in alkaline solution oxidizes it to dinitrosobenzene, whilst cold concentrated nitric acid oxidizes it to para-dinitrobenzene.

The zinc sulphate is added in order to remove the ferrocyanide formed as an insoluble zinc salt: 2K 3 Fe(NC)6+2KI=2K 4 Fe(NC) 6 -0 2.

ferrocyanide's Meaning':

salt of ferrocyanic acid usually obtained by a reaction of a cyanide with iron sulphate

Synonyms:

salt, potassium ferrocyanide, yellow prussiate of potash,

Antonyms:

dull,